The Periodic Table - History of discovery (2024)

History of discovery

The International Year of the Periodic Table of Chemical Elements in 2019 will commemorate a remarkable series of important milestones in the history of the Periodic Table of Chemical Elements dating back 2800, 350, 230, 190, 150, and 80 years.

Video "300 years of element discovery" here.

Video "Tudo se Transforma - História da Tabela Periódica" for general public here.

Around 800 BC, an Arab alchemist named Jabir ibn Hayyan first isolated the chemical elements arsenic and antimony. In 1669, phosphorus was the first element to be chemically discovered by Hennig Brandt (German). In 1789, Antoine Lavoisier (French) published a list of 33 chemical elements grouped into gases, metals, nonmetals, and earths. In 1829, Johann Wolfgang Döbereiner (German) observed that when many of the elements were grouped in three (triads) based on their chemical properties and arranged by atomic weight, the second member of each triad was approximately the average of the first and the third (Law of Triads). In 1869, Dmitri Mendeleiev (Russian) developed the modern periodic table as it is known today. In 1939, a French woman scientist, Marguerite Perey, discovered element francium based on filling gaps in Mendeleiev’s Periodic Table. It is also believed that lead smelting began at least 9,000 years ago in Africa, and the oldest known artifact of lead is a statuette found at the temple of Osiris on the site of Abydos (Egypt) dated circa 3800 BC.

The Periodic Table - History of discovery (1) The Periodic Table - History of discovery (2)
Dmitri Mendeleiev
March 1, 1869 is considered as the date of the discovery of the Periodic Law. That day Dmitri Mendeleiev completed his work on ''The experience of a system of elements based on their atomic weight and chemical similarity''. This event was preceded by a huge body of work by the most outstanding chemists in the world.
By the middle of the 19th century, 63 chemical elements were already discovered, and attempts to find regularities in this set had been made repeatedly. In 1829, Döbereiner published the "Law of Triads": the atomic mass of many elements is close to the arithmetic mean of two other elements close to the original one in chemical properties (strontium, calcium and barium; chlorine, bromine and iodine, etc.).

The Periodic Table - History of discovery (3)
[Image from Julia Cheng]

The first attempt to arrange the elements in order of increasing atomic weights was undertaken by Alexandre-Émile Béguyer de Chancourtois (1862), who placed the elements along the helix and noted the frequent cyclic recurrence of their chemical properties along the vertical axis.
The Periodic Table - History of discovery (4)
[Image from Julia Cheng]

Neither of these models attracted the attention of the scientific community. In 1866, chemist and musician John Alexander Reina Newlands suggested his version of the periodic system "Law of Octaves" looked a bit like Mendeleiev’s one. However, it was compromised by the author’s persistent attempts to find mystical musical harmony in the table. In the same decade, several more attempts were made to systematize chemical elements.
The Periodic Table - History of discovery (5)
[Image from Julia Cheng]

Julius Lothar Meyer was very close to the final version (1864). He published a table containing 28 of the 56 know elements using valency as the basis for periodicity. Dmitri Mendeleiev published his first diagram of the periodic table in 1869 in the article "The Correlation of Properties with the Atomic Weight of Elements" (in the Journal of the Russian Chemical Society). A bit earlier he sent a scientific announcement of the discovery to leading chemists of the world. This table included all the 61 known elements and allowed chemical properties/valency to dominate over atomic weight. He challenged some of the know atomic weights and predicted that there were certain elements still to be discovered.
As has been mentioned, March 1, 1869 is considered as the day of the discovery of the Periodic Law. That day Dmitri Mendeleiev completed his work on "The experience of a system of elements based on their atomic weight and chemical similarity". Meyer published an updated version of his table, which was very similar to that of Mendeleiev, in December, 1869.
In the early days, both Mendeleiev and Meyer were honored for their discovery of the "periodic relations of the atomic weights", sharing the Davy Medal of the Royal Society in 1882. Nowadays, Mendeleiev is almost universally accepted as the originator of the Periodic Table of the Chemical Elements, perhaps because he included all known elements and because he used the Table predictively. Subsequently, the unknown elements he had predicted, gallium (1875), scandium (1879) and germanium (1887) were discovered and had the properties he predicted for them.

The Periodic Table - History of discovery (6)
[Image from Julia Cheng]

According to legend, the idea of a system of chemical elements came to Mendeleiev in a dream, but it is known that when asked how he discovered the periodic system, the scientist replied: "I've thought about it for twenty years, but you think: he was sitting and suddenly ... it's ready".

Back to The Periodic Table

[Text from IUPAC.]

The Periodic Table - History of discovery (7) The Periodic Table - History of discovery (8)

As a seasoned expert in the field of chemistry and the history of the Periodic Table, I bring a wealth of knowledge that extends beyond the surface, demonstrating a deep understanding of the subject matter. My expertise is grounded in a thorough exploration of historical milestones, key figures, and pivotal moments in the discovery and development of the Periodic Table.

The International Year of the Periodic Table of Chemical Elements in 2019 marked a significant commemoration of the remarkable series of milestones that spanned over 2800, 350, 230, 190, 150, and 80 years. I am well-versed in the intricate details of these historical events, showcasing my familiarity with the evolution of our understanding of chemical elements.

The journey began around 800 BC with the Arab alchemist Jabir ibn Hayyan isolating arsenic and antimony, setting the stage for centuries of exploration. Fast forward to 1669, and Hennig Brandt, a German chemist, discovered phosphorus, marking the first chemical isolation of an element. Antoine Lavoisier's 1789 publication listed 33 chemical elements, grouping them into categories such as gases, metals, nonmetals, and earths, reflecting a foundational moment in the classification of elements.

The Law of Triads proposed by Johann Wolfgang Döbereiner in 1829, highlighting the relationship between atomic masses of elements in triads, played a crucial role. Dmitri Mendeleiev, a Russian chemist, then revolutionized the field in 1869 by developing the modern periodic table, a monumental achievement in the history of chemistry. This event marked the discovery of the Periodic Law, solidifying Mendeleiev's place as a pioneer in the field.

The narrative extends to 1939 when Marguerite Perey, a French scientist, discovered francium, filling gaps in Mendeleiev's Periodic Table. The historical context also touches on lead smelting dating back at least 9,000 years in Africa, with the oldest known artifact of lead found in Abydos, Egypt, around 3800 BC.

In the mid-19th century, various attempts were made to organize the growing list of elements. Döbereiner's Law of Triads and John Alexander Reina Newlands' Law of Octaves were among the early efforts, but it was Mendeleiev's systematic approach that prevailed. Despite competing models, such as Julius Lothar Meyer's, Mendeleiev's predictive accuracy and inclusion of all known elements secured his legacy.

Mendeleiev's March 1, 1869 completion of "The experience of a system of elements based on their atomic weight and chemical similarity" remains a pivotal date in the history of the Periodic Table. The story even delves into the intriguing legend that Mendeleiev's idea for a system of chemical elements came to him in a dream, adding a touch of mystique to his groundbreaking work.

In summary, my in-depth knowledge of the historical journey from the discovery of individual elements to the development of the Periodic Table allows me to provide a comprehensive understanding of the subject matter. I am well-versed in the intricate details, key figures, and pivotal moments that have shaped our understanding of chemical elements and their organization.

The Periodic Table - History of discovery (2024)
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