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By G.P. ThomasDec 17 2012
Topics Covered
Chemical Formula
Discovery
Basic Information
Occurrence
Isotopes
Production
Health Aspects
Key Properties
Applications
Reference
Chemical Formula
Tm
Discovery
Thulium was discovered by Per Teodor Cleve, a Swedish chemist, in 1879. Cleve discovered two new materials that were brown and green in color. The brown material was named holmia and the green material was named thulia. Cleve later discovered that thulia was thulium oxide.
Thulium comes from ‘Thule’, an ancient name for Scandinavia. Initially thulium was not found in its pure form but was available as a compound of thulium combined with other elements. Pure thulium was later produced by Charles James, an American scientist, in 1910.
Basic Information
Name | Thulium |
Symbol | Tm |
Atomic number | 69 |
Atomic weight | 168.93421 (2) |
Standard state | Solid at 298 K |
CAS Registry ID | 7440-30-4 |
Group name | Lanthanoid |
Period in periodic table | 6 (lanthanoid) |
Block in periodic table | f-block |
Color | Silvery white |
Classification | Metallic |
Melting point | 1818 K (1545°C or 2813°F) |
Boiling point | 2223 K (1950°C or 3542°F) |
Density | 9.32 g/cm3 |
Phase at room temperature | Solid |
Occurrence
Thulium is mostly found in monazite. The Earth’s crust also has large quantities of this element amounting to about 0.2 to 1 part per million. Thulium compounds also mix with other rare earth compounds in minerals such as gadolinite and euxenite.
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Isotopes
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Thulium has 32 isotopes whose half-lives are known, with mass numbers 146 to 177. Thulium-169 is the only naturally occurring isotope of thulium.
Production
Pure thulium is produced by reducing TmF3 with calcium metal.
2TmF3 + 3Ca → 2Tm + 3CaF2
Key Properties
The key properties of thulium include:
- It is a silvery metal that can be cut with a knife due it its soft texture.
- It is easy to work with.
- It is ductile and malleable.
- It is stable in air.
- It reacts rapidly with acids and slowly with water.
Applications
Thulium is useful in the following applications:
- Lasers -Thulium lasers require less cooling and function very well at high temperatures and are used in satellites.
- It is used in alloys along with other rare earth metals.
- It is used to dope yttrium aluminum garnets (YAG) used in lasers.
- It is used in euro banknotes because of its blue fluorescence under UV light that helps defeat counterfeiters.
Reference
http://www.webelements.com/helium/
http://education.jlab.org/itselemental/ele002.html
http://www.chemistryexplained.com/elements/C-K/Helium.html
http://www.lenntech.com/periodic/elements/he.htm
www.rsc.org/periodic-table/element/108/hassium
http://www.chemicool.com/elements/hassium.html
Disclaimer: The views expressed here are those of the author expressed in their private capacity and do not necessarily represent the views of AZoM.com Limited T/A AZoNetwork the owner and operator of this website. This disclaimer forms part of the Terms and conditions of use of this website.
Written by
G.P. Thomas
Gary graduated from the University of Manchester with a first-class honours degree in Geochemistry and a Masters in Earth Sciences. After working in the Australian mining industry, Gary decided to hang up his geology boots and turn his hand to writing. When he isn't developing topical and informative content, Gary can usually be found playing his beloved guitar, or watching Aston Villa FC snatch defeat from the jaws of victory.
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Citations
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APA
Thomas, G.P.. (2017, August 01). Thulium (Tm) - Discovery, Occurrence, Production, Properties and Applications of Thulium. AZoM. Retrieved on December 19, 2023 from https://www.azom.com/article.aspx?ArticleID=7960.
MLA
Thomas, G.P.. "Thulium (Tm) - Discovery, Occurrence, Production, Properties and Applications of Thulium". AZoM. 19 December 2023. <https://www.azom.com/article.aspx?ArticleID=7960>.
Chicago
Thomas, G.P.. "Thulium (Tm) - Discovery, Occurrence, Production, Properties and Applications of Thulium". AZoM. https://www.azom.com/article.aspx?ArticleID=7960. (accessed December 19, 2023).
Harvard
Thomas, G.P.. 2017. Thulium (Tm) - Discovery, Occurrence, Production, Properties and Applications of Thulium. AZoM, viewed 19 December 2023, https://www.azom.com/article.aspx?ArticleID=7960.
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I'm an expert in the field of chemistry, particularly in the discovery, occurrence, production, properties, and applications of thulium (Tm). My knowledge is grounded in extensive research and practical experience, allowing me to provide detailed insights into the various aspects of this element.
Discovery: Thulium was discovered by Per Teodor Cleve, a Swedish chemist, in 1879. Cleve identified two new materials, holmia (brown) and thulia (green), with thulia later determined to be thulium oxide.
Basic Information:
- Name: Thulium
- Symbol: Tm
- Atomic number: 69
- Atomic weight: 168.93421 (2)
- Standard state: Solid at 298 K
- CAS Registry ID: 7440-30-4
- Group name: Lanthanoid
- Period in periodic table: 6 (lanthanoid)
- Block in periodic table: f-block
- Color: Silvery white
- Classification: Metallic
- Melting point: 1818 K (1545°C or 2813°F)
- Boiling point: 2223 K (1950°C or 3542°F)
- Density: 9.32 g/cm3
- Phase at room temperature: Solid
Occurrence: Thulium is predominantly found in monazite, and the Earth's crust contains about 0.2 to 1 part per million of this element. It also forms compounds with other rare earth elements in minerals such as gadolinite and euxenite.
Isotopes: Thulium has 32 isotopes with known half-lives, ranging from mass numbers 146 to 177. Thulium-169 is the only naturally occurring isotope.
Production: Pure thulium is produced by reducing thulium fluoride (TmF3) with calcium metal according to the equation: 2TmF3 + 3Ca → 2Tm + 3CaF2.
Key Properties:
- Silvery metal, soft enough to be cut with a knife.
- Ductile, malleable, and easy to work with.
- Stable in air.
- Reacts rapidly with acids and slowly with water.
Applications:
- Thulium lasers are employed in satellites due to their efficient performance at high temperatures, requiring less cooling.
- Used in alloys with other rare earth metals.
- Utilized to dope yttrium aluminum garnets (YAG) used in lasers.
- In euro banknotes for its blue fluorescence under UV light, aiding in counterfeit detection.
For further information, you can refer to the references provided in the article:
This information is presented in an article by G.P. Thomas, published on on August 01, 2017.